Abstract a recent subsea failure of two subsea connectors made of uns s32760, a 25 wt% cr super duplex stainless steel, led to an extensive root cause failure analysis. Woollin p and murphy w, hydrogen embrittlement stress cracking of superduplex stainless steel, proc conf corrosion 2001, nace international, paper 01018. The cracking was accelerated by the incorporation of hydrogen into the steel. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. A small number of duplex and superduplex stainless steel components have failed in subsea service due to hydrogen induced stress cracking hisc. Damage due to hydrogen embrittlement and stress corrosion. Avoiding stress cracking of ferritic austenitic steels twi. Hydrogen induced stress cracking of duplex stainless steel. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. In this paper, experimental results on not only static responses, i. Delayed cracking also known as hydrogen induced cracking or cold cracking, occurs when the following three factors are present at the same time. Woollin p and gregori a, avoiding hydrogen embrittlement stress cracking of ferritic austenitic stainless steels under cathodic protection, proc conf omae 2004, paper 51203. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and carbonatebicarbonate solutions.
A recent subsea failure of two subsea connectors made of uns s32760, a 25 wt% cr super duplex stainless steel, led to an extensive root cause failure analysis. Hydrogen induced stress cracking in uns s32750 super duplex. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. This article discusses hydrogen embrittlement of carbon steel. The significance of these failures has led to research to define critical loading conditions for. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in. A corrosive medium especially chloridebearing or hydrogen sulphide h 2 s media. This is a complex topic, other factors, such as ph. H 2 s can cause corrosion of stainless steels such as 316 and 410 stainless in the form of sulfide stress cracking. Low temperature has been shown to have a significant effect on the hydrogenassisted fracture of type 316 stainless steel. The principal distinguishing feature of this type of crack is that it occurs in ferritic steels, most often immediately on welding or a short time after welding. Hydrogen sulfide cracking of carbon and alloy steels. Hydrogen enhanced localised plasticity help is a commonly cited failure mechanism used to explain this phenomenon 46. Hydrogen induced cracking of subsea duplex stainless steel.
Hydrogen induced stress cracking susceptibility of hyper duplex uns s33207 stainless steel tube. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. The corrosivity of hydrogen peroxide on stainless steel is minimal, so a. Also high strength structural steels which are welded are exposed to a certain hydrogen pickup which means a risk at fracture and blistering. It is also explained that how to test the damage due to hydrogen embrittlement in stainless steel. Stress corrosion cracking international institute of. This paper presents results from a test program examining the hisc susceptibility of 25% cr super duplex stainless steel uns s32750 at temperatures up to 150 0 c. Alloys which are suitable include 304, 304l, 316 and 316l. Stress corrosion cracking facts and how to reduce the. Astm f519 hydrogen embrittlement he testing element. Hydrogeninduced cracking hic in steel is a risk problem when steels are charged with hydrogen in service as in various hydrogen sulfide environments like sour oil and gas wells and some power plants. Hydrogen embrittlement of steel industrial metallurgists. Effects of hydrogen on the flow stress of type 316 stainless steel are discussed in detail in refs. Effect of temperature in hydrogen embrittlement in stainless steel, and fusion in inox steel.
Abstract effects of hydrogen on the stress corrosion cracking scc behavior of 304 and 310 stainless steels under sustained load were investigated in. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. Stress corrosion cracking and hydrogen embrittlement. Effects of hydrogen on the stress corrosion cracking scc behavior of 304 and 310 stainless steels under sustained load were investigated in boiling 42% mgcl2 solution. Effects of dissolved hydrogen and surface condition on the. Hydrogen stress cracking can affect several different types of metals such as high strength structural, carbon, and low alloy steels, along with titanium, nickel, and aluminium alloys. An illustration of cracking associated with the hydrogen embrittlement of austenitic stainless steel that is pulled in tension. The brittle nature of the fracture surface, calcareous deposits on the ferrule and exposure to cathodic protection suggested hydrogen induced stress cracking hisc. It was found that the threshold scc intensity factors of both 321 and 310 steels. Also known as sour service, issues including hydrogen blistering, hydrogen induced cracking hic and stress orientated hydrogen induced cracking sohic are caused by the aqueous hydrogen charging of the steel. Hydrogeninduced stress cracking of swaged super duplex stainless steel subsea components, corrosion. The factors of hydrogen embrittlement and ways to prevent it is. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials.
Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause. This cracking can also occur when ammonia is intentionally added to process streams as a neutralizer by someone unaware of its potential. When steel is embrittled and fails by cracking due to exposure to hydrogen in the presence of stress, the failure mechanism is known as hydrogen induced stress corrosion cracking hiscc 3. Technical reference on hydrogen compatibility of materials. Stress corrosion cracking and hydrogen embrittlement of. Stainless steel lowcarbon grades of stainless steel are excellent for the storage of hydrogen peroxide.
Defects hydrogen cracks in steels identification twi. It is clear that in both cases, cracking occurs at many locations. This article explains all about hydrogen embrittlment in stainless steel. The report will also include a compilation of available methods and main results of crack propagation rate for. Galvanically induced hydrogen stress cracking ghsc the presence of hydrogen introduced via corrosion in a metal may result in reduced ductility and increased susceptibility to cracking in the presence of tensile stress applied and or residual. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Hydrogen induced stress cracking susceptibility of hyper. Type 310 stainless steel in thin sections was embrittled by hydrogen. Modelling hydrogen induced stress corrosion cracking in. Hydrogen cracking in metastable austenitic stainless. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Ferritic stainless steels, on the other hand, tend to be fairly resistant to hydrogen stress cracking due to their comparatively low hardness. On the stress corrosion cracking and hydrogen embrittlement.
Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. This includes a discussion of the mechanism by which a steel becomes embrittled by hydrgogen, circumstances that lead to embrittlement, the effects of embrittlement on steel behavior, how to prevent the embrittlement, and tests for evaluating whether a steel has been embrittled. This report will comprise a compilation of the main mechanism for stress corrosion cracking and hydrogen embrittlement applied to prestressing steels. There is a growing acceptance of the term scc to co\er both mechanisms. Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in cooling water service that has been contaminated with ammonia due to biological growths or other contamination. Hydrogeninduced stress cracking of swaged super duplex stainless steel subsea components, corrosion 757. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides.
As an example of severe hydrogen embrittlement, the elongation at failure of 17 4ph precipitation hardened stainless steel was. Sulfide stress cracking an overview sciencedirect topics. It explains how hydrogen embrittlement occurs in stainless steel. Johnson, cornell university introduction 3 delayed failure, hydrogen embrittlement, and stress corrosion cracking 4 embrittlement kinetics and hydrogen transport 15 recapitulation 24 references 24 theories of hydrogen induced cracking of steels dr. Hydrogenenhanced stress corrosion cracking in stainless steel. This mode of attack is termed stress corrosion cracking scc.
Stainless steels are more resistant to general corrosion compared with carbon steel. Hydrogen cracking may also be called cold cracking or delayed cracking. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Smooth bar tensile properties of 316 at several temperatures between. Hydrogen embrittlement of austenitic stainless steel. Material, stress and environmental factors controlling sensitivity of ferritic austenitic stainless steels to hydrogen embrittlement stress cracking when exposed to. Hydrogen cracking in duplex stainless steel weld metal cracking sensitivity appears related to an excess of 50% delta ferrite in the weld by k. Experience has shown that stainless steels can suffer from hydrogen induced stress cracking hisc under cathodic protection in seawater. Hydrogen embrittlement overview on hydrogen degradation phenomena dr. Although hydrogeninduced cracking and stress corrosion cracking are similar phenomena, both types of damage are usually described and treated separately.
Hic steel hydrogen induced cracking supplier company. The effects of dissolved hydrogen dh and inner surface finish condition of the hollowed specimen on stress corrosion crack scc initiation and small crack growth behaviors of 316 stainless steel were investigated in high temperature water with various dh levels. Hydrogen stress cracking of high strength steels dtic. Hydrogen induced stress cracking hisc resistance and. Hydrogeninduced stress cracking of swaged super duplex. The failure of highstrength fasteners in aerospace equipment as a result of scc or hsc occurs infrequently and almost always unexpectedly.
Hisc is a term to refer to hydrogen stress cracking hsc of duplex and super duplex stainless steels dss and sdss, respectivelywhen exposed to hydrogen generated by cathodic. The interaction of corrosion fatigue and stresscorrosion. Stress corrosion cracking and hydrogen cracking are two important forms of environmental cracking which can cause serious failures in the oil and gas, pipeline, process and many other industries. Fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. Hydrogen cracking of ferriticaustenitic stainless steel. H2s can cause sulfide stress cracking of stainless steels. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. The differentiation between stress corrosion cracking and hydrogen stress cracking, and the effect of micro structure and composition of steels. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. The role of hydrogen in stresscorrosion cracking scc of austenitic stainless steel was investigated in boiling chloride solution.
Chloride stress corrosion cracking in austenitic stainless. A model has been developed which simulates the deformation of single crystal austenitic stainless steels and captures the effects of hydrogen on stress corrosion cracking. The role of hydrogen in stresscorrosion cracking of. Super duplex stainless steel structures subjected to cathodic protection are prone to hydrogen embrittlement.
Hydrogen induced cracking hic in steel is a risk problem when steels are charged with hydrogen in service as in various hydrogen sulfide environments like sour oil and gas wells and some power plants. Hydrogen induced stress cracking of swaged super duplex. Cracking occurred in welds containing 83% ferrite and hydrogen levels of 11. Properly passivated stainless steel provides a very stable surface for the storage of hydrogen peroxide. Other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking.
The role of hydrogen in the mechanism of stress corrosion cracking has been known since the 1970s so that preventative measures have since been introduced. Hydrogen cracking in duplex stainless steel weld metal. Hydrogeninduced cracking an overview sciencedirect topics. The term environmental stress cracking1 failures is also used sometimes. Hydrogen embrittlement and stress corrosion cracking. In this issue, the characteristic features and principal causes of hydrogen cracks are described. Pdf stress corrosion cracking and hydrogen cracking. This charging can cause blistering and embrittlement, which is potentially disastrous in carbon steel pressure vessel environments. The combination of tensile stress and a specific corrosive environment can crack stainless steels. The temperature and strain rate dependence of this embrittlement was almost analogous to that wellestablished for hydrogenated bodycentered cubic b. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. The programme sought to generate cracking data for sma welds, in 22%cr duplex stainless steel, for which the consumable hydrogen level had been determined using the vhe method.
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